4-Methylphenyl 1-thio-alpha-D-mannopyranoside CAS 457931-46-3
Thioglycosides are useful alternatives to glycosyl halides or trichloroacetimidates as glycosyl donors due to the robust nature of the anomeric thio moiety, which allows protecting group manipulation prior to glycosylation. 4-Methylphenyl 1-thio-alpha-D-mannopyranoside can be converted into various mannose donors.1-3
1. Watt, J. A.; Williams, S. Org. Biomol. Chem. 2005, 3, 1982-1992.
2. Nokami, T.; Shibuya, A.; Tsuyama, H.; Suga, S.; Bowers, A. A.; Crich, D.; Yoshida, J. J. Am. Chem. Soc. 2007, 129, 10922-10928.
3. Ye, X.-S.; Wong, C.-H. J. Org. Chem. 2000, 65, 2410-2431.
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